☰ Contents · Chemistry

The carbon group. Carbon

Lessons 8–9 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
9

Physical and chemical properties of carbon

Textbook: pp. 47–49
GoalKnow the physical and chemical properties of carbon, adsorption and its reducing action; write the reaction equations.
New words
adsorption · adsorbsiyaactivated carbon · faollashtirilgan ko‘mirreducing agent · qaytaruvchicarbide · karbid
Explanation

Carbon is an odourless, tasteless, hard-to-melt solid that does not dissolve in water; diamond melts at about 3550 °C. Charcoal and other carbons show adsorption: they take up gases and dissolved substances on their surface; activated carbon, whose surface is enlarged with steam, is used in gas masks and for purifying water and oils, and the gas mask was created by N.D. Zelinsky. At ordinary temperature carbon is fairly inactive, but when heated it burns: C + O₂ → CO₂ (with little oxygen 2C + O₂ → 2CO) and gives CS₂ with sulfur: C + 2S → CS₂. With metals it forms carbides: Ca + 2C → CaC₂; CaC₂ + 2H₂O → Ca(OH)₂ + C₂H₂ (acetylene), Al₄C₃ + 12HCl → 4AlCl₃ + 3CH₄. Carbon is a strong reducing agent: 2CuO + C → 2Cu + CO₂↑, 2Fe₂O₃ + 3C → 4Fe + 3CO₂↑. In Uzbekistan coal (brown coal and hard coal) is mined at Angren, Sharg‘un and Boysun. Carbon monoxide CO formed when coal burns is extremely poisonous, so coal must never be burned in a closed room.

Worked examples
To reduce 160 g of CuO (M = 80 g/mol, 2 mol) by 2CuO + C → 2Cu + CO₂ you need 1 mol, i.e. 12 g of carbon, and 128 g of copper forms.
Burning: 24 g of carbon (2 mol) burning completely by C + O₂ → CO₂ gives 2 mol of CO₂, i.e. 2 · 44 = 88 g.
Class activity

Observation (teacher demonstration only): the teacher shows adsorption with coloured water and an activated-carbon tablet (or filter). Students watch the colour fade and discuss why a larger carbon surface adsorbs better. Burning coal or experimenting with gases at home is forbidden.

Practice
1
What is adsorption?
2
How many moles of CO₂ form when 24 g of carbon burns completely? (M(C) = 12 g/mol)
3
Write the formulas of the carbides formed from Ca + C and from Al + C.
4
Why is carbon used to extract metals from their oxides?