☰ Contents · Chemistry

Silver, gold. The zinc subgroup

Lessons 31–32 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
31

Silver and gold: properties and uses

Textbook: pp. 137–138
GoalKnow the properties, production and uses of silver and gold; explain their chemical inertness.
New words
silver · kumushgold · oltinaqua regia · zar suvifineness mark · proba
Explanation

Silver (Ag, Z = 47) and gold (Au, Z = 79) are in the side subgroup of group I together with copper; both stand after hydrogen in the activity series, so they do not displace hydrogen from acids. Silver is a white, soft metal and the best conductor of electricity and heat; in compounds it is usually +1 (Ag⁺). It does not oxidise in air, but turns black under sulfur compounds (Ag₂S). Silver dissolves in concentrated HNO₃: Ag + 2HNO₃ → AgNO₃ + NO₂↑ + H₂O. AgNO₃ is a reagent for halide ions: Ag⁺ + Cl⁻ → AgCl↓ (white), AgBr is pale yellow; because AgBr is light-sensitive it has been used in photographic materials. Ag⁺ ions kill microbes. Gold is a yellow, very malleable metal of high density (19.3 g/cm³), occurs in nature mostly free (native), does not oxidise, and of the acids it dissolves only in aqua regia (a 1 : 3 mixture of HNO₃ and HCl). In industry gold is separated from ore by cyanidation; cyanides are extremely poisonous, so the process is strictly controlled. Because gold is soft, jewellery uses alloys with copper or silver; for example in an item stamped 750 gold makes up 75 %.

Worked examples
Ag + 2HNO₃ → AgNO₃ + NO₂↑ + H₂O: 108 g (1 mol) of Ag gives 170 g of AgNO₃; 216 g of Ag gives 340 g.
If the fineness mark is 375, gold is 37.5 %: 1000 g of the alloy contains 375 g of gold, the rest being copper and silver.
Class activity

Make a table in class for Cu, Ag, Au: colour, density, electrical conductivity, behaviour towards acids, uses. Write why gold coins and jewellery still shine after thousands of years. Chemical experiments (aqua regia, silver salts) are done only by the teacher.

Practice
1
In which reagent does gold dissolve and why not in other acids?
2
How many grams of AgNO₃ are obtained by dissolving 216 g of Ag in concentrated HNO₃? (A(Ag) = 108, M(AgNO₃) = 170)
3
How many grams of gold are in a 200 g item of fineness 750?
4
Why does jewellery use alloys of gold and not pure gold?