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Reactions in chemical production

Lessons 44 · 1 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
44

The importance of chemical reactions in industry

Textbook: pp. 189–191
GoalKnow the factors that control reaction rate and equilibrium in chemical production (temperature, pressure, concentration, catalyst) and carry out simple calculations.
New words
reaction rate · reaksiya tezligichemical equilibrium · kimyoviy muvozanatcatalyst · katalizatoryield · unum
Explanation

Every chemical production rests on a series of reactions, and the task of technology is to run them under the most favourable conditions. Reaction rate rises with temperature: for each 10 °C of heating the rate grows γ times (γ is the temperature coefficient), for example with γ = 2, going from 20 °C to 60 °C raises the rate 2⁴ = 16 times. A higher concentration of reagents also raises the rate: in 2NO + O₂ → 2NO₂, doubling the O₂ concentration doubles the rate, doubling the NO concentration raises it 2² = 4 times. A catalyst speeds up a reaction and is not used up. In reversible reactions chemical equilibrium is established; conditions are changed to shift it: for example, in N₂ + 3H₂ ⇌ 2NH₃ + Q, raising the pressure (4 volumes give 2 volumes) and removing the ammonia increase the yield; low temperature raises the yield but lowers the rate, so a catalyst (Fe), about 400–500 °C and high pressure are chosen. In sulfuric acid production 2SO₂ + O₂ ⇌ 2SO₃ runs with a catalyst (V₂O₅); for nitric acid ammonia is oxidised on a Pt catalyst: 4NH₃ + 5O₂ → 4NO + 6H₂O. The practical yield compared with the theoretical: η = m(practical)/m(theoretical) · 100 %. Scientists and enterprises in Uzbekistan work on mineral fertilisers, drug substances and polymers.

Worked examples
For 2SO₂ + O₂ → 2SO₃ with γ = 3, heating from 30 °C to 50 °C (two steps of 10 °C) raises the rate 3² = 9 times.
N₂ + 3H₂ → 2NH₃: 56 g (2 mol) of N₂ gives 4 mol, i.e. 68 g of NH₃. If 51 g is actually obtained, the yield is 51/68 · 100 = 75 %.
Class activity

Make a table: “Process” (NH₃ synthesis, SO₂ → SO₃, NH₃ oxidation), “Catalyst”, “Temperature and pressure”, “Why these conditions?”. Industrial reactions cannot be run at school; they involve high pressure, high temperature and poisonous gases, so watch demonstration videos and diagrams with the teacher.

Practice
1
If the temperature coefficient is 2, how many times does the rate grow when the temperature rises from 20 °C to 60 °C?
2
In 2NO + O₂ → 2NO₂, how many times does the rate grow if the NO concentration is tripled?
3
How many grams of NH₃ can theoretically be obtained from 112 g of N₂? (M(N₂) = 28, M(NH₃) = 17)
4
Why is a very low temperature not chosen for ammonia synthesis even though the yield would be higher?