☰ Contents · Chemistry

Production of metals. Alloys

Lessons 16–17 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
16

Occurrence, extraction and uses of metals

Textbook: pp. 71–73
GoalKnow the forms in which metals occur in nature, the methods of obtaining them (pyro-, hydro- and electrometallurgy) and their classification.
New words
metallurgy · metallurgiyaore · rudaferrous and non-ferrous metals · qora va rangli metallarnoble metals · nodir metallar
Explanation

Of the 118 elements, more than 90 are metals. Active metals occur in nature as salts (NaCl, CaCO₃), moderately active ones as oxides, sulfides and sulfates (Fe₂O₃, ZnS, PbS), and the least active — Cu, Ag, Au, Pt, Hg — partly or wholly in the free state. Metallurgy separates metals from their ores, and every process rests on oxidation and reduction. In pyrometallurgy an oxide is reduced at high temperature by C, CO, Al, Si or H₂: Fe₃O₄ + 4CO → 3Fe + 4CO₂, Cr₂O₃ + 2Al → Al₂O₃ + 2Cr. In hydrometallurgy a metal compound is brought into solution and displaced by a more active metal: CuSO₄ + Fe → FeSO₄ + Cu↓ (gold, silver, zinc and uranium are also obtained by hydrometallurgical methods). In electrometallurgy a melt or solution is electrolysed: alkali metals, alkaline-earth metals and aluminium are made like this (Na⁺ + e⁻ → Na). Iron and its alloys are ferrous metals and the rest non-ferrous; metals with density below 5 g/cm³ are light (Li, Na, Mg, Al) and the denser ones heavy (Cu, Pb, Hg); gold, silver and platinum are noble metals. Uzbekistan has ores of gold (Muruntau and other deposits in the Kyzylkum), silver, copper, tungsten and other metals, and the Almalyk Mining and Metallurgical Complex produces copper and other non-ferrous metals.

Worked examples
Fe₃O₄ + 4CO → 3Fe + 4CO₂: 232 g Fe₃O₄ (1 mol) gives 3 mol, i.e. 3 · 56 = 168 g of iron.
Cr₂O₃ + 2Al → Al₂O₃ + 2Cr: 152 g Cr₂O₃ (1 mol) gives 2 · 52 = 104 g of chromium. Aluminium is the reducing agent because it is more active than chromium (aluminothermy).
Class activity

“Metal passport”: make a card for one metal you choose (Fe, Cu, Al, Au or Zn): occurrence, method of production, uses, ferrous/non-ferrous, light/heavy. The cards are shown in a class display. Only a notebook, coloured pencils and a book are needed.

Practice
1
Which metals occur free in nature?
2
By Fe₃O₄ + 4CO → 3Fe + 4CO₂, how many grams of iron come from 232 g Fe₃O₄? (M(Fe₃O₄) = 232)
3
Which kind of metallurgy is the Cr₂O₃ + 2Al reaction and why?
4
Why are sodium and aluminium obtained by electrolysis rather than reduction by carbon?