GoalKnow when ion-exchange reactions go to completion; write molecular, full ionic and net ionic equations; use qualitative tests for ions.
New words
ion-exchange reaction · ion almashinish reaksiyasinet ionic equation · qisqa ionli tenglamaprecipitate · cho‘kmaneutralisation · neytrallash
Explanation
In electrolyte solutions reactions go on between ions, and a reaction goes to completion only if at least one product is an insoluble precipitate, a gas or a weak electrolyte (such as water). We write the equation in three forms: molecular; full ionic (strong electrolytes as ions, precipitates, gases and weak electrolytes as molecules); and net ionic (identical ions on both sides are cancelled). The essence of neutralisation is H⁺ + OH⁻ → H₂O, so HCl + KOH and HNO₃ + NaOH have the same net ionic equation. Ba²⁺ + SO₄²⁻ → BaSO₄↓ detects the sulfate ion, Ag⁺ + Cl⁻ → AgCl↓ the chloride ion and Cu²⁺ + 2OH⁻ → Cu(OH)₂↓ the copper(II) ion; CO₃²⁻ gives CO₂ gas with an acid, and Na⁺ colours a flame yellow and K⁺ violet. If all ions stay free in solution (e.g. KCl with NaNO₃) there is no reaction. Experiments, especially with acids and alkalis, are shown or supervised by the teacher only.
Pb(NO₃)₂ + 2KI → PbI₂↓ + 2KNO₃ (yellow precipitate). Net ionic: Pb²⁺ + 2I⁻ → PbI₂↓. Mass calculation: 208 g BaCl₂ (1 mol) with excess Na₂SO₄ gives 233 g BaSO₄, because M(BaSO₄) = 233 g/mol.
Class activity
“Will it react?” Cards list pairs of solutions: CuSO₄ + NaOH, KCl + NaNO₃, Na₂CO₃ + HNO₃, BaCl₂ + K₂SO₄. Students use the solubility table to decide whether a precipitate, gas or water forms and write the net ionic equation. Only paper and the solubility table.
Practice
1
Write the net ionic equation for the reaction of CuSO₄ and NaOH solutions.
Cu²⁺ + 2OH⁻ → Cu(OH)₂↓ (blue precipitate).
2
Do solutions of KCl and NaNO₃ react when mixed? Give the reason.
No: no precipitate, gas or weak electrolyte forms, so all ions remain in solution.
3
How many grams of AgCl precipitate when 340 g AgNO₃ (2 mol) reacts with excess NaCl? M(AgCl) = 143.5 g/mol.
287
4
Why are the net ionic equations of HCl + KOH and HNO₃ + NaOH the same?
In both only H⁺ and OH⁻ combine to form water; the other ions are unchanged.