☰ Contents · Chemistry

Electrolytes and their dissociation

Lessons 3–4 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
3

Electrolytes and non-electrolytes

Textbook: pp. 20–23
GoalTell electrolytes from non-electrolytes; explain the main idea of electrolytic dissociation and the role of polar water molecules.
New words
electrolyte · elektrolitnon-electrolyte · noelektrolitelectrolytic dissociation · elektrolitik dissotsiatsiyahydroxonium ion H₃O⁺ · gidroksoniy ioni H₃O⁺
Explanation

Substances whose solution or melt conducts electric current are electrolytes; those that do not are non-electrolytes. Electrolytes include water-soluble acids, alkalis and salts; sugar, alcohol, methane and distilled water are non-electrolytes. Solid NaCl does not conduct because its ions are locked in the crystal lattice. In water the polar water molecules attract the ions, pull them out of the crystal and surround them (hydration), giving freely moving ions — this is electrolytic dissociation. When current passes, cations move to the cathode and anions to the anode, so the solution conducts through the movement of ions. Acids ionise when their polar molecules interact with water; the hydrogen ion attaches to a water molecule to form H₃O⁺, usually written simply as H⁺. Atoms and ions differ sharply: unlike poisonous Cl₂, the Cl⁻ ion in table salt is harmless.

Worked examples
KCl → K⁺ + Cl⁻; Na₃PO₄ → 3Na⁺ + PO₄³⁻. 1 mol Na₃PO₄ gives 3 mol Na⁺ and 1 mol PO₄³⁻.
Cl₂ gas is poisonous while the Cl⁻ ion in table salt is not: Cl⁻ has a stable 8-electron shell and its properties are entirely different from those of the atom.
Class activity

Teacher demonstration: the teacher dips the electrodes of a conductivity tester into dry salt, distilled water, salt solution and sugar solution in turn. Students watch the lamp and record “conducts / does not conduct” in a table. Only the teacher runs it; students must never experiment with electricity at home.

Practice
1
Which of these are electrolytes: sugar, NaOH, CH₄, K₂SO₄?
2
Write the dissociation equation of Al₂(SO₄)₃.
3
How many moles of Na⁺ ions form when 2 mol Na₃PO₄ dissociates completely in water?
4
Why does dry table salt not conduct current while its solution does?