☰ Contents · Chemistry

Protecting the atmosphere and hydrosphere

Lessons 42 · 1 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
42

Protecting the atmosphere and the hydrosphere

Textbook: pp. 180–184
GoalKnow the main pollutants of the atmosphere and hydrosphere, the cleaning methods (dust capture, water treatment) and the chemistry of acid rain.
New words
pollution · ifloslanishacid rain · kislotali yomg‘irwaste water · oqova suvpesticide · pestitsid
Explanation

Air is polluted by natural causes (volcanoes, dust), burning of fuel, industry and transport, and burning of waste; poisonous gases such as NO, NO₂, CO, SO₂, Cl₂, H₂S, HCl, HF and dust enter the air. Electrostatic precipitators, adsorbents and wetting the area (the wet method) are used to capture dust and aerosols. Acid rain forms like this: sulfur in fuel becomes SO₂ (S + O₂ → SO₂), which is oxidised to SO₃ and gives sulfuric acid with water (2SO₂ + O₂ → 2SO₃; SO₃ + H₂O → H₂SO₄); nitrogen oxides give nitric acid (4NO₂ + O₂ + 2H₂O → 4HNO₃). Such rain harms plants, soil, buildings and metals; to reduce it, fuel should be freed of sulfur and gases captured. Drinkable water is a very small part of the water on Earth, so we must save it and treat waste water: water is filtered, then lime (Ca(OH)₂) and Al₂(SO₄)₃ are added, and the Al(OH)₃ precipitate carries impurities down (Al₂(SO₄)₃ + 3Ca(OH)₂ → 2Al(OH)₃↓ + 3CaSO₄), and it is disinfected with chlorinated lime. Pesticides (insecticides, fungicides, herbicides) are used against pests, but they do not break down quickly and may accumulate in soil, water and food and poison, so only specialists work with them, following safety rules.

Worked examples
S + O₂ → SO₂: 32 g of S gives 64 g of SO₂. If 2000 kg of coal has 1 % S, 20 kg of S burns to 40 kg of SO₂.
Al₂(SO₄)₃ + 3Ca(OH)₂ → 2Al(OH)₃↓ + 3CaSO₄: 342 g (1 mol) of Al₂(SO₄)₃ gives 156 g (2 mol) of Al(OH)₃.
Class activity

Environment survey: find sources of pollution of air, water and soil (transport, rubbish, waste water) around your school or neighbourhood and draw a map; write 3 proposals to reduce them. Do not burn waste or throw it into water bodies; do not experiment with chemicals.

Practice
1
How does acid rain form? Write the equations for SO₂.
2
4000 kg of coal contains 2 % sulfur. How many kg of SO₂ form on burning? (A(S) = 32, M(SO₂) = 64)
3
How many grams of Al(OH)₃ do 684 g of Al₂(SO₄)₃ precipitate in water treatment? (M(Al₂(SO₄)₃) = 342, M(Al(OH)₃) = 78)
4
Why does the Al(OH)₃ precipitate clean water?