☰ Contents · Chemistry

Steel. Practical work 3

Lessons 39–40 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
39

Steel production

Textbook: pp. 168–176
GoalKnow the chemistry of making steel from cast iron, the kinds of steel and their uses; solve problems that find a formula from a crystal hydrate or an oxide.
New words
steel · po‘latalloy steel · legirlangan po‘latconverter · konverterhardening · toblash
Explanation

Steel is an iron alloy with up to 2.14 % carbon (in practice usually below 1.5 %); making it from cast iron means reducing most of the carbon and the harmful impurities (S, P, Si, Mn). Oxygen is blown into molten cast iron: first some iron is oxidised: 2Fe + O₂ → 2FeO, then FeO oxidises the impurities: FeO + C → Fe + CO↑, 2FeO + Si → 2Fe + SiO₂, FeO + Mn → Fe + MnO, 5FeO + 2P → 5Fe + P₂O₅. The oxides go into the slag; sulfur is bound by FeS + CaO → CaS + FeO, phosphorus by 3CaO + P₂O₅ → Ca₃(PO₄)₂. Today steel is made mainly in basic oxygen converters and electric arc furnaces; these have almost entirely replaced the open-hearth furnaces that were once widespread. By composition steel is carbon or alloy steel; alloying additions are Cr, Ni, Mo, V, W, Ti. By purpose we distinguish structural steel (machine parts, bridges, buildings), tool steel (cutting tools) and special steels (stainless, heat-resistant); heating and cooling (hardening) change the hardness of steel. In chemistry problems we often find a formula: from the mass of water lost on heating a crystal hydrate we find n, and from the dissolving of a metal oxide in acid we find the atomic mass of the metal.

Worked examples
FeSO₄·nH₂O: heating 27.8 g of the crystal hydrate lost 12.6 g of water. FeSO₄ = 15.2 g = 0.1 mol, water = 12.6/18 = 0.7 mol, n = 7: FeSO₄·7H₂O.
Divalent metal oxide MeO: dissolving 112 g of MeO took 146 g of HCl (4 mol). MeO + 2HCl → MeCl₂ + H₂O: 2 mol of MeO, M = 112/2 = 56, A = 56 − 16 = 40: calcium.
Class activity

Make a table: for cast iron and steel give carbon content, properties, uses and production. Sort steel objects (tool, bridge, knife, medical instrument) into groups: structural, tool, stainless. Hardening of steel is done only by an instructor in suitable conditions; do not heat or burn anything as an experiment at home.

Practice
1
What is reduced when steel is made from cast iron, and why?
2
How many grams of FeO are needed to oxidise 36 g of carbon by FeO + C → Fe + CO? (M(FeO) = 72, A(C) = 12)
3
2000 kg of cast iron contains 4 % C. How many kg of carbon are removed if carbon is cut to 1 % (take the mass as unchanged)?
4
What is alloy steel, and which metal is added to make stainless steel?