☰ Contents · Chemistry

Soda production. Calcium and magnesium

Lessons 23–24 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
23

Soda production

Textbook: pp. 105–108
GoalDistinguish the kinds of soda (calcined, crystalline, baking, caustic); know the essence of the Leblanc and Solvay processes and the uses of soda.
New words
calcined (anhydrous) soda · kalsinatsiyalangan sodacrystalline (washing) soda · kristall sodaammonia (Solvay) process · ammiakli usulcrystal hydrate · kristallogidrat
Explanation

Soda, Na₂CO₃, is widely used in glass, soap, paper, textiles, the oil industry and daily life, but it is rare in nature, so it is synthesised. Anhydrous Na₂CO₃ is calcined soda, Na₂CO₃·10H₂O (M = 286 g/mol) is crystalline or washing soda, NaHCO₃ is baking soda and NaOH is caustic soda — these are different substances. In the Leblanc (sulfate) process table salt is converted to Na₂SO₄ with sulfuric acid, reduced with coal to Na₂S, and Na₂S is heated with limestone to give soda: 2NaCl + H₂SO₄ → Na₂SO₄ + 2HCl, Na₂SO₄ + 2C → Na₂S + 2CO₂, Na₂S + CaCO₃ → Na₂CO₃ + CaS; it was costly and was displaced. In the Solvay (ammonia) process a saturated NaCl solution is saturated with ammonia and carbon dioxide, and sparingly soluble NaHCO₃ precipitates: NaCl + NH₃ + CO₂ + H₂O → NaHCO₃↓ + NH₄Cl; heating it gives soda: 2NaHCO₃ → Na₂CO₃ + CO₂ + H₂O. Ammonia is regenerated from NH₄Cl with slaked lime: 2NH₄Cl + Ca(OH)₂ → 2NH₃ + CaCl₂ + 2H₂O, and CO₂ comes from roasting limestone, which makes the process economical. The Kungrad Soda Plant in Karakalpakstan produces various soda products.

Worked examples
572 g of crystalline soda (2 mol Na₂CO₃·10H₂O) contains 2 · 106 = 212 g of anhydrous soda and 2 · 180 = 360 g of water.
Solvay process: heating 2 mol NaHCO₃ (168 g) gives 1 mol Na₂CO₃ (106 g), 1 mol CO₂ and 1 mol H₂O; the CO₂ is returned to the process.
Class activity

“Sort the sodas”: cards show Na₂CO₃, Na₂CO₃·10H₂O, NaHCO₃, NaOH and the names (calcined, crystalline, baking, caustic) with uses. Teams match them up. Reminder: caustic soda and washing soda can harm skin and eyes; only adults handle them.

Practice
1
Write the formula and molar mass of crystalline soda.
2
How many grams of anhydrous soda remain when 572 g of crystalline soda is dehydrated? (M(Na₂CO₃) = 106)
3
Which substance precipitates in the Solvay process, and why?
4
Why is the Solvay process cheaper than the Leblanc process?