☰ Contents · Chemistry

The periodic law and periodic system

Lessons 1 · 1 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
1

The periodic system of elements and the periodic law

Textbook: pp. 5–15
GoalKnow the modern wording of the periodic law; place an element in the table from its electron formula and explain how properties change along periods and down groups.
New words
periodic law · davriy qonunnuclear charge · yadro zaryadivalence electrons · valent elektronlarelectron shell · elektron pog‘ona
Explanation

On 1 March 1869 D.I. Mendeleev discovered the periodic law and at first tied it to atomic masses. Later Thomson discovered the electron (1897) and Moseley showed that the nuclear charge equals the atomic number (1913), so the modern wording is: the properties of elements and of their simple and compound substances depend periodically on the charge of the atomic nuclei. The period number equals the number of electron shells, and in main subgroups the group number equals the number of outer electrons (helium is an exception). The maximum number of electrons in a shell is 2n² (n is the shell number), and the subshells s, p, d, f are filled in the order 1s → 2s → 2p → 3s → 3p → 4s → 3d … Across a period from left to right the nuclear charge grows, the atomic radius shrinks, and ionisation energy and electron affinity increase, so metallic properties weaken and nonmetallic ones strengthen. Down a group the radius grows, outer electrons are held more weakly and metallic properties strengthen; the strongest metal is caesium and the strongest nonmetal is fluorine.

Worked examples
Sulfur, Z = 16: electron formula 1s²2s²2p⁶3s²3p⁴. There are three shells, so period 3; six outer electrons, so main group VI; it is a nonmetal.
Na, Mg, Al are in one period: nuclear charges +11, +12, +13 and the radius falls, so metallic character weakens from Na to Al. Li, Na, K are in one group: the radius grows, so K is the most metallic.
Class activity

“Table relay”: split the class into two teams. Team members take turns placing the symbols of elements with Z = 3, 9, 12, 17, 19 on an empty periodic table on the board and saying each electron formula. The faster, more accurate team wins. No experiments: only chalk and a board.

Practice
1
State the modern periodic law.
2
Write the electron formula of the atom with Z = 17 and give its period and group.
3
What is the maximum number of electrons on the third shell?
4
Why is Mg less metallic than Na?