☰ Contents · Chemistry

Aluminium

Lessons 27–28 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 9, revised 4th edition. “O‘zbekiston” NMIU, Tashkent, 2019
27

Aluminium

Textbook: pp. 121–123
GoalKnow where aluminium occurs in nature, how it is produced (electrolysis of an alumina–cryolite melt) and how it is used.
New words
aluminium · aluminiybauxite · boksitcryolite · kriolitalumina · aluminiy oksid (glinozyom)
Explanation

Aluminium is in the main subgroup of group III, period 3, has 3 electrons in its outer shell and shows the oxidation state +3 in compounds (Al³⁺). It is the most abundant metal in the Earth's crust and occurs in nature only as compounds: bauxite, alunite, kaolin (clay), feldspar. In industry pure Al₂O₃ (alumina) is separated from bauxite and electrolysed dissolved in molten cryolite Na₃AlF₆ at about 950 °C, because cryolite sharply lowers the melting temperature. At the cathode Al³⁺ + 3e⁻ → Al; at the anode oxygen is released and burns the carbon anode to CO₂; the overall equation is 2Al₂O₃ → 4Al + 3O₂ (electrolysis). The process needs a great deal of electricity, so it is done where electricity is cheap. Aluminium is light (density about 2.7 g/cm³) and conducts electricity and heat well, so it is used for wires, aircraft and car parts, cookware and foil.

Worked examples
2Al₂O₃ → 4Al + 3O₂: 204 g (2 mol) of Al₂O₃ gives 108 g (4 mol) of Al, so 102 g of Al₂O₃ gives 54 g of Al.
Producing 1 mol of Al needs 3 mol of electrons at the cathode (Al³⁺ + 3e⁻ → Al); 2 mol of Al needs 6 mol of electrons.
Class activity

Find aluminium objects (wire, foil, cookware, window frame) and make a table: “Object” and “Property that makes it suitable” (lightness, heat conduction, corrosion resistance). Do not test aluminium with acids or alkalis at home.

Practice
1
Does aluminium occur free in nature? Which of its minerals do you know?
2
How many grams of Al are obtained by electrolysis of 306 g of Al₂O₃? (M(Al₂O₃) = 102, A(Al) = 27)
3
What happens at the cathode and at the anode?
4
Why is Al₂O₃ dissolved in cryolite?