☰ Contents · Chemistry

Electronegativity. The covalent bond

Lessons 14–15 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
15

Types of chemical bond. Polar and nonpolar covalent bond

Textbook: pp. 66–70
GoalKnow nonpolar and polar covalent bonds, the donor–acceptor mechanism, and electron and structural formulas of molecules.
New words
covalent bond · kovalent bog‘lanishnonpolar and polar bond · qutbsiz va qutbli bog‘structural formula · tuzilish (grafik) formuladonor–acceptor bond · donor-akseptor bog‘
Explanation

If atoms are linked by shared electron pairs, the bond is called covalent. Between identical atoms (H₂, Cl₂, O₂, N₂) the shared pair sits in the middle — the bond is nonpolar; between atoms whose electronegativities differ slightly (HCl, H₂O, NH₃, CH₄) the pair shifts towards the atom with higher EN — the bond is polar and the atoms carry partial charges (δ⁺, δ⁻). Each shared pair is written as one line: H–H, O=O, N≡N, H–Cl; the number of shared pairs equals the valency of the element. In a donor–acceptor bond one atom (the donor) supplies the shared pair from its own unshared pair and the other (the acceptor) supplies an empty orbital: NH₃ + H⁺ → NH₄⁺, H₂O + H⁺ → H₃O⁺. The bond formed is no different from an ordinary covalent bond. Noble gases are single atoms because their outer shell is already complete.

Worked examples
Cl₂: each Cl has 7 outer electrons; one shared pair gives both 8: Cl–Cl, a nonpolar bond. N₂: 3 shared pairs, N≡N, nitrogen is trivalent.
NH₄⁺: the nitrogen in ammonia has one unshared pair, H⁺ has an empty 1s orbital; N is the donor, H⁺ the acceptor. In the ammonium ion N forms four bonds, its oxidation state remains –3.
Class activity

“Pair game”: build models of Cl₂, HCl, H₂O, N₂ with two-coloured beads or paper circles; join the shared pairs with thread and mark polar/nonpolar. Only paper, thread and beads.

Practice
1
In which of H₂, HCl, O₂, H₂S is the bond nonpolar?
2
How many shared electron pairs are in the N₂ molecule?
3
Write the structural formula of H₂S and name the bond type.
4
By which mechanism is NH₄⁺ formed? Name the donor and the acceptor.