☰ Contents · Chemistry

Reaction rate. Chemical equilibrium

Lessons 34–35 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
34

Rate of chemical reactions

Textbook: pp. 141–143
GoalKnow the concept of reaction rate and the factors that affect it (concentration, temperature, surface, nature of reactants, catalyst).
New words
reaction rate · reaksiya tezligiconcentration · konsentratsiyacatalyst · katalizatorinhibitor · ingibitor
Explanation

The rate of a chemical reaction is the change in concentration of a reacting substance per unit of time: v = (c₁ – c₂) : t, in mol/(l·s). The higher the concentration, the more often particles collide and the faster the reaction: sulfur burns much faster in pure oxygen than in air. Each 10 °C of heating usually raises the rate 2–4 times (γ times): v₂ = v₁ · γ^((t₂ – t₁) : 10). For solids the rate depends on the exposed surface: a powder reacts faster than a lump. The nature of the substances matters too: potassium reacts with water faster than sodium, and copper does not react at all (these experiments only with the teacher). A catalyst speeds up a reaction without being used up (MnO₂ in the decomposition of H₂O₂, V₂O₅ in the oxidation of SO₂); an inhibitor slows a reaction down, for instance protecting metal from rusting. Sometimes a reaction must be speeded up (in industry), sometimes slowed down (rusting, food spoiling).

Worked examples
A concentration falls from 8 mol/l to 2 mol/l in 4 s: v = (8 – 2) : 4 = 1.5 mol/(l·s). In another reaction from 8 to 2 in 3 s: v = (8 – 2) : 3 = 2 mol/(l·s).
If γ = 3, heating by 30 °C raises the rate 3³ = 27 times. If at 20 °C a reaction takes 54 minutes, at 50 °C it is finished in 54 : 27 = 2 minutes.
Class activity

“Sugar and heat”: at home with an adult (no hot water, only lukewarm tap water): put the same amount of cube sugar and granulated sugar into identical glasses of cold and lukewarm water and note in how many seconds each dissolves. Fill a table and say which factor raised the rate. No chemicals are used; do not drink it.

Practice
1
What is reaction rate and what is its unit?
2
A concentration falls from 8 to 2 mol/l in 3 seconds. Find the rate.
3
If γ = 4, how many times does the rate rise when heated by 20 °C?
4
Why does powdered marble react faster than a lump?