☰ Contents · Chemistry

Chlorine

Lessons 23 · 1 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
23

Chlorine

Textbook: pp. 96–99
GoalKnow chlorine’s position in the periodic table, its preparation, properties and uses; explain the safety rules for working with chlorine.
New words
chlorine · xlorchlorine water · xlorli suvelectrolysis · elektroliztoxic gas · zaharli gaz
Explanation

Chlorine Cl is an element of period 3, the main subgroup of group VII, atomic number 17, shells 2, 8, 7; its molecule Cl₂ has a nonpolar covalent bond (Cl–Cl). In nature it occurs only in compounds: rock salt NaCl, sylvite KCl, carnallite and others. In industry chlorine is made by electrolysis of a salt solution: 2NaCl + 2H₂O → 2NaOH + Cl₂ + H₂. Chlorine is a yellowish-green, sharp-smelling, choking, poisonous gas; about 2.5 times heavier than air, partly soluble in water (chlorine water). Being a strong oxidizing agent it reacts with sodium 2Na + Cl₂ → 2NaCl, with iron 2Fe + 3Cl₂ → 2FeCl₃ (Fe is oxidized to +3) and with hydrogen H₂ + Cl₂ → 2HCl. With water and alkali one atom is the oxidizing and the other the reducing agent: Cl₂ + H₂O → HCl + HClO. Chlorine is used to disinfect drinking water, bleach cloth, and make plastics and hydrochloric acid. Only a teacher or specialist works with chlorine in a fume cupboard; it must never be smelled.

Worked examples
2Fe + 3Cl₂ → 2FeCl₃: Fe⁰ – 3e⁻ → Fe³⁺ | 2; Cl₂⁰ + 2e⁻ → 2Cl⁻ | 3. Six electrons are transferred in all. The molar mass of Cl₂ is 2·35.5 = 71 g/mol, 1 mol at s.t.p. is 22.4 l.
2NaCl + 2H₂O → 2NaOH + Cl₂ + H₂: 2 mol NaCl (2·58.5 = 117 g) give 1 mol Cl₂ (22.4 l). So 234 g NaCl give 2 mol of chlorine, i.e. 142 g Cl₂.
Class activity

“Chlorine safety poster”: on A3 paper draw and write chlorine’s properties, uses and safety rules (goggles, gloves, fume cupboard, never smell, hazard sign). No experiment with chlorine is done at home, and cleaning products (chlorine bleach) are never mixed.

Practice
1
How is chlorine made in industry?
2
Name the oxidizing and reducing agent in 2Na + Cl₂ → 2NaCl.
3
What is the mass of 2 mol Cl₂ (M = 71 g/mol)?
4
Why is it dangerous to keep chlorine in an open vessel in a room or to smell it?