☰ Contents · Chemistry

Electronegativity. The covalent bond

Lessons 14–15 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
14

Relative electronegativity of chemical elements

Textbook: pp. 64–65
GoalKnow electronegativity, how it changes in periods and subgroups, and find the direction in which a shared electron pair shifts.
New words
electronegativity · elektromanfiylikrelative electronegativity · nisbiy elektromanfiylik (NEM)shared electron pair · umumiy elektron juftgiving and accepting electrons · elektron berish va olish
Explanation

The outer electrons of metals are held weakly, so metals give electrons away easily; nonmetals tend to accept electrons. Electronegativity is the ability of an atom in a chemical bond to attract the shared electron pair. Its absolute value is awkward to calculate, so relative values are used; on a convenient scale fluorine is 4.0, oxygen 3.44, chlorine 3.16, nitrogen 3.04, carbon 2.55, hydrogen 2.20, sodium 0.93 and caesium 0.79. Along a period from left to right the nuclear charge grows, the radius shrinks and electronegativity rises; down a main subgroup the radius grows and electronegativity falls. So the most electronegative element is fluorine and the lowest are caesium and francium. The shared electron pair shifts from the atom with lower electronegativity to the one with higher; the latter becomes partly negative, the former partly positive.

Worked examples
Across period 3 electronegativity rises: Na 0.93 < Mg 1.31 < Al 1.61 < Si 1.90 < P 2.19 < S 2.58 < Cl 3.16.
In H–Cl, EN(Cl) = 3.16 > EN(H) = 2.20, so the shared pair shifts towards Cl: chlorine is partly negative, hydrogen partly positive.
Class activity

“Tug of war”: two students pull a rope — if the strength is equal the marker stays in the middle (same EN), if one is stronger the marker moves to that side (different EN). Compare with H₂ and HCl. Under teacher supervision, with care.

Practice
1
What does electronegativity express?
2
Write C, N, O, F in order of increasing electronegativity.
3
Towards which atom does the electron pair shift in H₂O?
4
Why is fluorine the most electronegative element?