☰ Contents · Chemistry

Hydrochloric acid. Fluorine, bromine, iodine

Lessons 27–28 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
27

Hydrochloric acid

Textbook: pp. 116–120
GoalKnow the properties of hydrochloric acid, the qualitative test for the chloride ion, and the importance of chlorides.
New words
hydrochloric acid · xlorid kislotachloride · xloridqualitative test · sifat reaksiyasiprecipitate · cho‘kma
Explanation

Hydrochloric acid is a solution of hydrogen chloride in water. The concentrated acid (about 37 %, density 1.19 g/cm³) is a colourless, sharp-smelling liquid that fumes in moist air. It shows the general properties of acids: it turns litmus red, reacts with metals before hydrogen (Zn, Fe, Mg) giving a salt and hydrogen (Zn + 2HCl → ZnCl₂ + H₂), reacts with basic oxides (CaO + 2HCl → CaCl₂ + H₂O) and bases giving a salt and water, and releases carbon dioxide from carbonates (CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂). The qualitative test for the chloride ion is silver nitrate, which gives a white curdy precipitate of AgCl: Ag⁺ + Cl⁻ → AgCl↓. The precipitate dissolves neither in water nor in nitric acid. Most chlorides dissolve well in water (AgCl and PbCl₂ hardly do). Table salt NaCl is used in food, food preservation and the chemical industry, and KCl is a potassium fertilizer. Hydrochloric acid is always handled by the teacher or an adult, with goggles and gloves.

Worked examples
NaCl + AgNO₃ → AgCl↓ + NaNO₃. Full ionic equation: Na⁺ + Cl⁻ + Ag⁺ + NO₃⁻ → AgCl↓ + Na⁺ + NO₃⁻; net: Ag⁺ + Cl⁻ → AgCl↓. M(AgCl) = 108 + 35.5 = 143.5 g/mol.
CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂↑: 100 g CaCO₃ (1 mol) give 1 mol CO₂ (22.4 l); 500 g give 5 mol, i.e. 5·22.4 = 112 l CO₂. 73 g HCl in 365 g solution: ω = 73 : 365 · 100 % = 20 %.
Class activity

“Reaction cards”: on 6 cards write HCl with Zn, CaO, NaOH, CaCO₃, Cu and AgNO₃. Predict which react and where a gas or precipitate forms (copper stands after hydrogen — no reaction). On paper only; they are tested in class by the teacher.

Practice
1
Name two general acid properties of hydrochloric acid.
2
What is the reagent for the chloride ion and what is the result?
3
Zn + HCl and Cu + HCl: which goes? Write the equation.
4
Why does the AgCl precipitate not dissolve even in nitric acid and why is this useful?