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The periodic law

Lessons 5 · 1 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
5

The periodic law of chemical elements

Textbook: pp. 25–29
GoalExplain the discovery of the periodic law, its original and modern wording, and how periodicity shows up.
New words
periodic law · davriy qonunnuclear charge · yadro zaryadiatomic number · tartib raqamiperiodicity · davriylik
Explanation

In 1869 D.I. Mendeleev arranged the elements in order of increasing atomic mass, noticed that properties repeat after a certain interval, and formulated the periodic law. Earlier, scientists such as Döbereiner (triads), de Chancourtois (cylindrical table), Newlands (octaves) and Meyer had also looked for patterns. Across the third period from Na to Cl, the highest-oxide valency rises from I to VII (Na₂O, MgO, Al₂O₃, SiO₂, P₂O₅, SO₃, Cl₂O₇), metallic character weakens and nonmetallic character grows, and the period ends with the noble gas argon; the next element, K, is again an alkali metal. Argon (Aᵣ ≈ 40) is heavier than potassium (Aᵣ ≈ 39), yet by properties argon must come first; this showed that properties depend on nuclear charge, not on atomic mass. The modern wording: the properties of elements and of the simple and compound substances they form depend periodically on the charge of the atomic nucleus. The atomic number equals the number of protons in the nucleus.

Worked examples
The element with atomic number 15 is phosphorus: nuclear charge +15, highest oxide P₂O₅ (valency V), hydrogen compound PH₃ (valency III); 5 + 3 = 8.
Ar and K: Aᵣ(Ar) ≈ 40 > Aᵣ(K) ≈ 39, but nuclear charges are +18 and +19. By charge Ar is 18th and K 19th, so periodicity is kept.
Class activity

“Periodicity chain”: write H, He, Li ... Ar on cards numbered 1 to 18, lay them in rows of 8 and notice that the alkali metals fall in one column. Paper only.

Practice
1
State the modern periodic law in your own words.
2
Formula of the highest oxide and hydrogen compound of the Group VI element in period 3?
3
Find the relative molecular mass of SO₃.
4
Why is argon placed before potassium although it is heavier?