☰ Contents · Chemistry

Hydrogen chloride

Lessons 24 · 1 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
24

Hydrogen chloride

Textbook: pp. 100–102
GoalKnow the structure, preparation, properties and uses of hydrogen chloride.
New words
hydrogen chloride · vodorod xloridrelative molecular mass · nisbiy molekular massarelative density · nisbiy zichlikhydrochloric acid · xlorid kislota
Explanation

Hydrogen chloride HCl is a polar covalent molecule (H–Cl) with relative molecular mass Mᵣ = 1 + 35.5 = 36.5. It is a colourless, sharp-smelling, choking gas; its density relative to air is 36.5 : 29 ≈ 1.26, i.e. slightly heavier than air. It fumes in moist air because its vapour forms a fine mist with the moisture. It dissolves extremely well in water: 1 volume of water takes about 500 volumes of HCl, and this solution is hydrochloric acid. In industry it is made from hydrogen and chlorine: H₂ + Cl₂ → 2HCl; in the laboratory conc. H₂SO₄ is heated with dry NaCl: 2NaCl + H₂SO₄ → Na₂SO₄ + 2HCl (only a teacher does this, in a fume cupboard). Dry hydrogen chloride does not react with metals or metal oxides, which sets it apart from hydrochloric acid. Its chief use is making hydrochloric acid.

Worked examples
Mᵣ(HCl) = 1 + 35.5 = 36.5. 2 mol NaCl (117 g) give 2 mol HCl, i.e. 2·36.5 = 73 g of gas. 5 mol NaCl give 5 mol HCl, at s.t.p. 5·22.4 = 112 l.
H₂ + Cl₂ → 2HCl: the gas volumes are in the ratio 1 : 1 : 2. So 10 l H₂ react with 10 l Cl₂ and give 20 l HCl (under the same conditions).
Class activity

“Fountain” as a drawing: in your notebook sketch the HCl dissolving experiment: a flask of gas, a tube, water. Write why water shoots in (the gas dissolves and the pressure drops). Only the teacher demonstrates; no gas is made at home.

Practice
1
Find Mᵣ of hydrogen chloride and its density relative to air.
2
How is HCl made in industry? Write the equation.
3
What volume do 5 mol HCl occupy at s.t.p.?
4
Why does a solution of HCl in water behave as an acid while the dry gas does not react with metals?