☰ Contents · Chemistry

First classification of elements and natural families

Lessons 3–4 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
3

First classification of chemical elements

Textbook: pp. 17–20
GoalUnderstand the first classification of elements into metals, nonmetals and amphoteric elements, and its limits.
New words
metals · metallarnonmetals · metallmaslaramphoteric element · amfoter elementamphoteric hydroxide · amfoter gidroksid
Explanation

The foundations of chemistry were laid by ancient Greek thinkers (Leucippus, Democritus, Epicurus) and by medieval scholars — al-Razi, al-Farabi, Beruni, Ibn Sina — who tried to group substances by their properties. About 30 elements were known at the end of the 18th century, 63 by the 1860s, and 118 today. Elements were first split by outward signs into metals and nonmetals: metals are shiny, conduct heat and electricity and are malleable (all solid except mercury); nonmetals lack these properties and are solid (S, C), liquid (Br₂) or gaseous (O₂, H₂, Cl₂). Hydroxides of typical metals are bases, those of nonmetals are acids. For amphoteric elements such as zinc and aluminium, the hydroxide reacts with both acids and alkalis: Zn(OH)₂ + 2HCl → ZnCl₂ + 2H₂O and Zn(OH)₂ + 2NaOH → Na₂ZnO₂ + 2H₂O. This classification is not perfect: chromium forms CrO (basic), Cr₂O₃ (amphoteric) and CrO₃ (acidic).

Worked examples
Classifying: Na is a metal (oxide Na₂O basic, hydroxide NaOH a base); S is a nonmetal (oxide SO₂ acidic, acid H₂SO₃); Zn is amphoteric (ZnO and Zn(OH)₂ amphoteric).
To neutralise 0.5 mol of Zn(OH)₂ we need 2 · 0.5 = 1 mol of HCl, since Zn(OH)₂ + 2HCl → ZnCl₂ + 2H₂O.
Class activity

“Metal or nonmetal?”: the teacher shows pictures or samples in closed containers (copper wire, sulfur powder, aluminium foil, charcoal); the class fills a properties table. Do not touch mercury or other chemicals; only the teacher handles samples.

Practice
1
List the physical properties typical of metals.
2
Which two reactions prove that zinc hydroxide is amphoteric?
3
What properties do the oxides CrO, Cr₂O₃ and CrO₃ of chromium have?
4
Why is the “metal–nonmetal” division not perfect?