☰ Contents · Chemistry

Redox reactions

Lessons 19–20 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
20

Writing equations of redox reactions

Textbook: pp. 83–88
GoalKnow how to balance redox equations by the electron balance method.
New words
electron balance · elektron balanselectrons given · berilgan elektronlarelectrons accepted · olingan elektronlarcoefficient · koeffitsiyent
Explanation

In the electron balance method the numbers of electrons given and accepted are made equal. Steps: 1) write the scheme; 2) find the elements whose state changes; 3) write a half-reaction for each: Al⁰ – 3e⁻ → Al³⁺, 2H⁺ + 2e⁻ → H₂⁰; 4) find the least common multiple of the electron numbers and put extra multipliers (2 for Al, 3 for H); 5) write these as coefficients for the oxidizing and reducing agents; 6) balance the remaining atoms (metal, acid residue, hydrogen, oxygen). Result: 2Al + 6HCl → 2AlCl₃ + 3H₂. At the end each element must have equal atom numbers on both sides. These equations are written on paper only; the experiment of a metal with acid is never done at home.

Worked examples
Mg + O₂ → MgO: Mg⁰ – 2e⁻ → Mg²⁺ | 2; O₂⁰ + 4e⁻ → 2O²⁻ | 1. Multipliers 2 and 1 (LCM 4): 2Mg + O₂ → 2MgO.
Fe₂O₃ + CO → Fe + CO₂: 2Fe³⁺ + 6e⁻ → 2Fe⁰ | 1; C²⁺ – 2e⁻ → C⁴⁺ | 3. Result: Fe₂O₃ + 3CO → 2Fe + 3CO₂; 6 electrons are transferred in total.
Class activity

“Scales”: use two sheets of paper as pans: write “electrons given” on the left and “electrons accepted” on the right. Balance Cu + AgNO₃ → Cu(NO₃)₂ + Ag with cards (each card = 1 electron). Paper only.

Practice
1
What is the aim of the electron balance method?
2
Balance Cu + AgNO₃ → Cu(NO₃)₂ + Ag.
3
How many electrons are transferred in total in 4Al + 3O₂ → 2Al₂O₃?
4
Why is the least common multiple of the electron numbers used?