☰ Contents · Chemistry

Atomic structure of small- and large-period elements

Lessons 11–12 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
12

Atomic structure of the elements of large periods

Textbook: pp. 49–50
GoalKnow the atomic structure of elements of periods 4–7 (large periods), d- and f-elements, and the shortened electron formula.
New words
large period · katta davrd-elements · d-elementlarf-elements (lanthanides, actinides) · f-elementlar (lantanoidlar, aktinoidlar)shortened formula [Ar] · qisqartirilgan formula [Ar]
Explanation

Large periods consist of two rows (even and odd). Period 4 starts with potassium (K): K 2, 8, 8, 1 — 1s² 2s² 2p⁶ 3s² 3p⁶ 4s¹; in Ca the 4s sublevel is filled (4s²). From scandium (Z = 21) to zinc (Z = 30) the electrons fill the inner 3d sublevel — these are d-elements (10 of them): Sc ...3d¹ 4s², Zn ...3d¹⁰ 4s². From gallium to krypton (Z = 31–36) the 4p sublevel fills, and in Kr the outer shell ends with 8 electrons. So period 4 has 2 s-, 10 d- and 6 p-elements, 18 in all. In periods 6 and 7 the 4f and 5f sublevels fill: the 14 elements after lanthanum and actinium are the lanthanides and actinides (f-elements). A formula can be shortened: potassium [Ar] 4s¹, caesium [Xe] 6s¹. A few elements such as chromium and copper have one electron in the outer shell (4s¹); these deviations are studied later.

Worked examples
Zinc (Z = 30): 2, 8, 18, 2; 1s² 2s² 2p⁶ 3s² 3p⁶ 3d¹⁰ 4s² or [Ar] 3d¹⁰ 4s². Two outer electrons — a metal, a d-element.
Arsenic (Z = 33): 2, 8, 18, 5 (2 + 8 + 18 + 5 = 33); [Ar] 3d¹⁰ 4s² 4p³; period 4, Group V, a p-element. Highest oxide As₂O₅, hydrogen compound AsH₃.
Class activity

“Layer strip”: draw a long strip for period 4 and mark the elements from K to Kr: 2 s, 10 d, 6 p. Colour each type with coloured pencils. Drawing only.

Practice
1
How many d-elements are in period 4?
2
Check the electron total for manganese (Z = 25) with the distribution 2, 8, 13, 2.
3
Shortened electron formula of bromine (Z = 35)?
4
Why are lanthanides and actinides called f-elements?