☰ Contents · Chemistry

Electron shells and energy sublevels

Lessons 9–10 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
10

Energy sublevels

Textbook: pp. 42–45
GoalKnow the s-, p-, d-, f- sublevels, the number of orbitals and electrons in them, and the basics of writing electron formulas.
New words
energy sublevel · energetik pog‘ona (qavatcha)orbital · orbitals-, p-, d-, f-elements · s-, p-, d-, f- elementlarelectron formula · elektron formula
Explanation

Within a shell, electrons are divided into sublevels by the shape of their clouds: s (spherical, 1 orbital, 2 electrons), p (dumbbell-shaped, 3 orbitals, 6 electrons), d (5 orbitals, 10 electrons), f (7 orbitals, 14 electrons). Each orbital holds at most two electrons spinning in opposite directions. Shell n has n sublevels: shell 1 has 1s; shell 2 has 2s, 2p; shell 3 has 3s, 3p, 3d; shell 4 has 4s, 4p, 4d, 4f. Electrons fill the lower-energy sublevel first, so 4s fills before 3d. In an electron formula the number of electrons is written as a superscript: boron is 1s² 2s² 2p¹. Elements are called s-, p-, d- or f-elements depending on which sublevel is filled last (14 s, 36 p, 40 d and 28 f elements, 118 in total).

Worked examples
Capacity of shell 3: 3s (2) + 3p (6) + 3d (10) = 18 electrons — this agrees with 2n² = 18.
Carbon (Z = 6): 1s² 2s² 2p². Magnesium (Z = 12): 1s² 2s² 2p⁶ 3s². Carbon is a p-element, magnesium an s-element.
Class activity

“Orbital hotel”: draw rooms for each sublevel (s — 1, p — 3, d — 5, f — 7 rooms, 2 beds each). Place the electrons of N (Z = 7) and Ne (Z = 10). Drawing only.

Practice
1
How many orbitals and how many electrons can a p sublevel have?
2
How many electrons fit at most into the 3 p-orbitals?
3
Write the electron formula of oxygen (Z = 8).
4
Why does the 4s sublevel fill before 3d?