☰ Contents · Chemistry

Composition of the nucleus. Isotopes

Lessons 7–8 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
8

Isotopes. Isobars

Textbook: pp. 36–38
GoalKnow isotopes, isobars and isotones; calculate the average relative atomic mass from a mixture of isotopes.
New words
isotopes · izotoplarisobars · izobarlarisotones · izotonlaraverage (mean) value · o‘rtacha arifmetik qiymat
Explanation

Isotopes are kinds of atoms with the same number of protons (same nuclear charge) but different numbers of neutrons; they occupy one cell of the periodic table and have the same chemical properties. Hydrogen has three isotopes: protium ¹H, deuterium ²H and tritium ³H (tritium is radioactive and is used only in special laboratories). Because natural elements are mixtures of isotopes, the relative atomic mass is fractional: Aᵣ = A₁ · w₁ + A₂ · w₂ + …, where w is the fraction of an isotope. For example, copper is a mixture of ⁶³Cu (69 %) and ⁶⁵Cu (31 %), giving Aᵣ ≈ 63.6. Isobars have the same mass number but different nuclear charge (¹⁴C and ¹⁴N), and isotones have the same number of neutrons (¹⁴C and ¹⁶O, both with 8 neutrons).

Worked examples
Lithium: ⁶Li 7.5 %, ⁷Li 92.5 %. Aᵣ = 6 · 0.075 + 7 · 0.925 = 0.45 + 6.475 = 6.925 ≈ 6.9.
Magnesium: ²⁴Mg 79 %, ²⁵Mg 10 %, ²⁶Mg 11 %. Aᵣ = 24 · 0.79 + 25 · 0.10 + 26 · 0.11 = 18.96 + 2.5 + 2.86 = 24.32 ≈ 24.3.
Class activity

“Isotope cards”: cards show ¹H, ²H, ³H, ³⁵Cl, ³⁷Cl, ¹⁴C, ¹⁴N, ¹⁶O; label pairs as isotopes, isobars or isotones and write the numbers of protons and neutrons. Paper only.

Practice
1
How do isotopes differ and what do they share?
2
How many neutrons are in the ³⁷Cl isotope (Z = 17)?
3
An element has two isotopes: mass number 79 (50 %) and 81 (50 %). Find the average Aᵣ.
4
Why are the relative atomic masses of elements often fractional?