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Mineral fertilizers

Lessons 46–47 · 2 lessons · I.R. Asqarov, K. G‘opirov, N.X. To‘xtaboyev. Chemistry Grade 8, revised 4th edition. “Yangiyul Poligraph Service”, Tashkent, 2019
47

The most important mineral fertilizers

Textbook: pp. 189–193
GoalKnow the formulas, preparation and properties of the most important nitrogen, phosphorus and potassium fertilizers; calculate the nutrient content of a fertilizer.
New words
saltpetre (nitrate fertilizer) · selitrasuperphosphate · superfosfatpotassium chloride · kaliy xloridurea · karbamid
Explanation

Nitrogen fertilizers: sodium saltpetre NaNO₃, potassium saltpetre KNO₃, ammonium nitrate NH₄NO₃ (ω(N) = 35 %), ammonium sulfate (NH₄)₂SO₄, urea CO(NH₂)₂ (ω(N) ≈ 47 %). Ammonium nitrate is made by acting on ammonia with nitric acid: NH₃ + HNO₃ → NH₄NO₃; it absorbs moisture and is dangerous with flammable materials, so it must be kept dry and separate. Phosphorus fertilizers: phosphorite meal (Ca₃(PO₄)₂, insoluble in water, for acid soils), simple superphosphate Ca(H₂PO₄)₂ · CaSO₄ (Ca₃(PO₄)₂ + 2H₂SO₄ → Ca(H₂PO₄)₂ + 2CaSO₄), double superphosphate Ca(H₂PO₄)₂ (Ca₃(PO₄)₂ + 4H₃PO₄ → 3Ca(H₂PO₄)₂, 40–50 % P₂O₅), precipitate CaHPO₄ · 2H₂O, bone meal, and the complex ammophos (a mixture of NH₄H₂PO₄ and (NH₄)₂HPO₄). Potassium fertilizers: KCl (52–60 % K₂O), sylvinite KCl · NaCl, kainite, potassium nitrate and plant ash (mainly K₂CO₃). The chlorine in sylvinite and kainite harms some plants, so the dose is not exceeded. Ammonium fertilizers are not put on limed soil, since ammonia escapes. Many fertilizers are produced at chemical plants in our country.

Worked examples
NH₃ + HNO₃ → NH₄NO₃: 17 g + 63 g = 80 g. For 800 kg of NH₄NO₃ you need 800·63 : 80 = 630 kg HNO₃ and 800·17 : 80 = 170 kg NH₃.
Ca₃(PO₄)₂ + 2H₂SO₄ → Ca(H₂PO₄)₂ + 2CaSO₄: 310 g + 196 g = 506 g of products (mass is conserved: 234 + 272). Urea CO(NH₂)₂: Mᵣ = 12 + 16 + 2·(14 + 2) = 60; ω(N) = 28 : 60 ≈ 0.47.
Class activity

“Fertilizer table”: for 12 fertilizers make a table: name, formula, nutrient element, condition of use (e.g. not for limed soil), storage rule. Calculate the nutrient content for 3 of them. Only a book, notebook and calculator.

Practice
1
Order NH₄NO₃, (NH₄)₂SO₄ and urea by nitrogen content (about 35, 21, 47 %).
2
How is simple superphosphate made? Give the equation.
3
What mass of K₂O is in 298 kg KCl (2KCl → K₂O: 149 → 94)?
4
Why must ammonium nitrate be kept away from flammable materials?