☰ Contents · Chemistry (Organic chemistry)

High-molecular compounds and laboratory work

Lessons 35–36 · 2 lessons · A. Mutalibov, E. Murodov, S. Masharipov, H. Islomova. Organic Chemistry, Grade 10, 1st edition. G‘afur G‘ulom Publishing House, Tashkent, 2017
36

Laboratory work

Textbook: pp. 153–156
GoalExplain the aims, observations and reaction equations of the textbook’s laboratory works and state the safety rules.
New words
laboratory work · laboratoriya ishiobservation · kuzatishconclusion · xulosasafety rules · xavfsizlik texnikasi
Explanation

Laboratory works are done only under the teacher’s instruction and supervision, with safety goggles, gloves and a lab coat, in a ventilated room; reagents are used in small amounts, nothing is tested by taste or smell, and concentrated acids and alkalis stay in the teacher’s hands. The textbook works are: (1) preparing ethylene by heating ethanol with concentrated H₂SO₄ and testing it with bromine water: C₂H₅OH → C₂H₄ + H₂O; (2) preparing acetylene by adding water to CaC₂ and observing its sooty flame: CaC₂ + 2H₂O → C₂H₂ + Ca(OH)₂; (3) dissolving glycerol in water and its deep-blue solution with freshly precipitated Cu(OH)₂; (4) preparing acetic acid from sodium acetate, its reaction with Mg and Zn (faster with Mg) and its decolourizing of NaOH + phenolphthalein: CH₃COOH + NaOH → CH₃COONa + H₂O; (5) the reaction of glucose with Cu(OH)₂ (blue solution in alkali, red precipitate on heating); (6) starch paste and its blue colour with iodine; (7) the biuret test of a protein (alkali + a little CuSO₄ — violet). Works that produce flammable gases (ethylene, acetylene) or heat concentrated sulfuric acid (1, 2, 4) are demonstrated by the teacher only. After each work the observation, equation and conclusion are written in the notebook; the workplace is cleaned and waste is collected as the teacher directs. Repeating these works at home is strictly forbidden.

Worked examples
Observation for burning acetylene: a bright sooty flame, because the carbon content is high. Equation: 2C₂H₂ + 5O₂ → 4CO₂ + 2H₂O (complete combustion). Calculation: 64 g of CaC₂ (1 mol) gives 26 g of C₂H₂.
Sample report (glucose + Cu(OH)₂): observation — first a blue solution, on heating a red precipitate; conclusion — glucose showed polyhydric-alcohol properties (blue solution) and aldehyde properties (Cu₂O).
Class activity

Make a lab-report template in your notebook: aim, reagents, observation, equation, conclusion, safety. Then complete it for one experiment shown by the teacher (or by video) in class.

Practice
1
Write the equation for making ethylene from ethanol.
2
How many grams of acetylene can be obtained from 192 g of CaC₂ (M(CaC₂) = 64, M(C₂H₂) = 26)?
3
What common result do glycerol and glucose give with Cu(OH)₂?
4
Why must the laboratory works not be repeated at home?