☰ Contents · Chemistry (Organic chemistry)

History of organic chemistry and the structure theory

Lessons 1–2 · 2 lessons · A. Mutalibov, E. Murodov, S. Masharipov, H. Islomova. Organic Chemistry, Grade 10, 1st edition. G‘afur G‘ulom Publishing House, Tashkent, 2017
1

History of organic chemistry. Characteristic features of organic compounds

Textbook: pp. 4–6
GoalDescribe how organic chemistry became a science and state the characteristic features of organic compounds.
New words
organic chemistry · organik kimyosynthesis · sintezcovalent bond · kovalent bog‘non-electrolyte · noelektrolit
Explanation

In the early 1800s chemists sorted substances into two groups by where they came from: those obtained from rocks and minerals, and those from plants and animals (organic substances); the second group was thought to arise only in living organisms under a special “vital force”. Laboratory syntheses disproved this: F. Wöhler made oxalic acid from dicyan in 1824 and urea from ammonium cyanate in 1828; A. Kolbe synthesized acetic acid, M. Berthelot a fat, and A. M. Butlerov a sugar-like substance from formaldehyde. Organic chemistry is the science of the structure, preparation and properties of hydrocarbons and their derivatives. Organic compounds are distinguished by carbon atoms joining each other and other elements by covalent bonds into long chains. They burn to give CO₂ and H₂O, melt and decompose more easily than inorganic salts, mostly do not dissociate into ions in solution (non-electrolytes), and their reactions are usually slow. Another feature is isomerism: substances with the same composition but different structure exist.

Worked examples
Burning of ethanol: C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O. Both sides have C: 2, H: 6, O: 7 atoms, so the equation is balanced. The products are carbon dioxide and water.
Wöhler’s synthesis: NH₄OCN → CO(NH₂)₂. Ammonium cyanate (an inorganic salt) and urea (organic) have the same composition, CH₄N₂O; the molar mass of urea is M = 12 + 16 + 2·(14 + 2) = 60 g/mol.
Class activity

Split the class into two teams and play “inorganic or organic?”: one team writes names of everyday materials (sugar, table salt, cotton, glass, vinegar, candle wax) and the other guesses their class from what they know about burning and solubility. Nothing is burned — work only with pictures and names.

Practice
1
From which substance did F. Wöhler synthesize urea in 1828?
2
What is the molar mass of urea CO(NH₂)₂ in g/mol (C = 12, O = 16, N = 14, H = 1)?
3
Balance the reaction C₃H₈ + O₂ → CO₂ + H₂O.
4
Why are reactions between organic substances usually slower than those between inorganic salts?