☰ Contents · Chemistry (Organic chemistry)

Petroleum and its refining

Lessons 18 · 1 lessons · A. Mutalibov, E. Murodov, S. Masharipov, H. Islomova. Organic Chemistry, Grade 10, 1st edition. G‘afur G‘ulom Publishing House, Tashkent, 2017
18

Natural sources of hydrocarbons. Petroleum and its refined products

Textbook: pp. 69–73
GoalDescribe the composition of petroleum, the fractions of fractional distillation, cracking and refined products.
New words
petroleum (crude oil) · neftfractional distillation · fraksion haydashfuel oil (mazut) · mazut (qoramoy)cracking · kreking
Explanation

Petroleum is an oily mixture of gaseous, liquid and solid hydrocarbons; its colour ranges from yellow to black, it is lighter than water and insoluble in it, and it has no sharp boiling point because it is a mixture. Besides hydrocarbons it contains sulfur, oxygen and nitrogen compounds. By fractional distillation it is separated by boiling range: up to about 150 °C gasoline (petrol, C₅–C₉), 150–300 °C kerosene (about C₉–C₁₆), above 300 °C fuel oil (mazut); mazut gives lubricating oils, petroleum jelly and paraffin, and the residue tar gives asphalt. Straight-run distillation yields little petrol, so heavy fractions are cracked: C₁₆H₃₄ → C₈H₁₈ + C₈H₁₆, C₈H₁₈ → C₄H₁₀ + C₄H₈. Thermal cracking uses high temperature and pressure; catalytic cracking uses a catalyst and gives more branched alkanes. Burning petroleum products releases CO₂ and SO₂ and pollutes the air, so economy and cleaner fuels matter. Uzbekistan has petroleum refineries, for example in the Fergana and Bukhara regions.

Worked examples
In cracking C₁₀H₂₂ → C₅H₁₂ + C₅H₁₀ mass is conserved: 142 g of decane gives 72 g of pentane and 70 g of pentene (72 + 70 = 142).
Combustion of octane: 2C₈H₁₈ + 25O₂ → 16CO₂ + 18H₂O. 114 g of octane (1 mol) gives 8 mol, i.e. 352 g, of CO₂.
Class activity

Make a product map: place products you know (petrol, kerosene, lubricating oil, paraffin, asphalt) into the list of fractions and note where each is used. No experiments; do not play with petroleum products.

Practice
1
What is the fraction that distils up to about 150 °C called?
2
Cracking 142 g of decane C₁₀H₂₂ gave 72 g of pentane. What is the mass of pentene formed?
3
How many grams of CO₂ form when 114 g of octane burn (M(C₈H₁₈) = 114, M(CO₂) = 44)?
4
Why does petroleum not boil at one single temperature like a pure substance?