☰ Contents · Physics

Amount of substance and molar mass

Lessons 3–4 · 2 lessons · P. Habibullayev, A. Boydedayev, A. Bahromov, K. Suyarov, J. Usarov, M. Yuldasheva. Physics Grade 9, revised and expanded 3rd edition. G‘afur G‘ulom Publishing House, Tashkent, 2019
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Amount of substance

Textbook: pp. 12–15
GoalKnow amount of substance, the mole, Avogadro’s constant and molar mass; use N = νN_A, ν = m/M and n = N/V.
New words
amount of substance · modda miqdorimole · molAvogadro constant · Avogadro doimiysimolar mass · molyar massa
Explanation

A macroscopic body contains an enormous number of particles, so their number is compared with the number of atoms in a standard sample: 12 g of carbon. One mole is the amount of substance containing (almost exactly) as many particles as there are atoms in 12 g of carbon-12. This number is the Avogadro constant N_A ≈ 6.02·10²³ mol⁻¹, the same for all substances; since 2019 the mole has been defined by fixing this constant at exactly 6.02214076·10²³. The amount of substance is denoted ν (nu) and measured in moles: ν = N/N_A, so N = νN_A. The mass of one mole is the molar mass M: M = m₀N_A (unit kg/mol); numerically, in g/mol, M equals M_r, e.g. M = 18 g/mol for water. For a substance of mass m, ν = m/M; the number of molecules per unit volume is the concentration n = N/V (unit m⁻³), and ρ = n·m₀.

Worked examples
In 36 g of water the amount of substance is ν = m/M = 36 g / 18 g/mol = 2 mol. The number of molecules is N = νN_A = 2·6.02·10²³ ≈ 1.2·10²⁴.
The mass of 0.5 mol of carbon dioxide CO₂: M = 44 g/mol, m = νM = 0.5·44 = 22 g. One CO₂ molecule has mass m₀ = M/N_A = 0.044 kg/mol / 6.02·10²³ mol⁻¹ ≈ 7.3·10⁻²⁶ kg.
Class activity

“Mole” cards: the teacher writes two substances (e.g. water and carbon dioxide) and a mass on the board; groups calculate the amount of substance and the number of molecules, and the first with the correct answer shows it. Only paper and pencil; no chemicals are used.

Practice
1
State the value and unit of the Avogadro constant.
2
Find the amount of substance in 450 g of water (M = 18 g/mol). Give the answer in mol.
3
What is the mass of 6 mol of oxygen O₂ (M = 32 g/mol)? Answer in grams.
4
Why is the molar mass numerically equal to the relative molecular mass (in g/mol)?