☰ Contents · Physics

Electrolysis problems and uses

Lessons 44–45 · 2 lessons · P.Q. Habibullayev, A. Boydedayev, A.D. Bahromov, J.E. Usarov, K.T. Suyarov, M.K. Yuldasheva. Physics, textbook for Grade 8 of general secondary schools, revised and enlarged 3rd edition. “O‘qituvchi” Publishing and Printing Creative House, Tashkent, 2019
45

Uses of electrolysis in daily life and technology

Textbook: pp. 127–129
GoalKnow applications of electrolysis: copper refining, galvanostegy and galvanoplasty.
New words
refining · rafinirlashgalvanostegy · galvanostegiyagalvanoplasty · galvanoplastikacoating · qoplama
Explanation

Electrolysis is widely used in industry. In copper refining an impure copper block is made the anode and pure copper the cathode; when current passes, the anode dissolves and pure copper collects on the cathode. Pure copper is important for wires because impurities raise the resistivity. In galvanostegy an object is made the cathode and coated with a thin layer of another metal (such as nickel, chromium or gold) — this protects from rust or decorates. In galvanoplasty a metal layer is deposited on a mould of an object to obtain an exact metal copy; the method was discovered in 1838 by the Russian scientist B. S. Jacobi. Aluminium is also obtained by electrolysis of a melt. Such work is done in factories by specialists, with poisonous solutions, wearing protective equipment.

Worked examples
In a refining bath the current is 1000 A and the time 1000 s: q = 10⁶ C. The mass of copper m = 0.329 · 10⁶ = 329 000 mg = 329 g.
Nickel plating with S = 50 cm², h = 0.002 cm, ρ ≈ 9 g/cm³: m = 9 · 50 · 0.002 = 0.9 g = 900 mg. With k = 0.3 mg/C and I = 1 A, t = 900 : 0.3 = 3000 s = 50 min.
Class activity

Observe objects around you with galvanic coatings (a nickel- or chromium-plated tap, a key) and write why they are coated. Do not try coating yourself.

Practice
1
In electrolytic copper refining, which electrode becomes covered with pure copper?
2
How do galvanostegy and galvanoplasty differ?
3
How many grams of copper (k = 0.329 mg/C) are released when 1000 A flows for 1000 s?
4
Why is copper refined for electric wires?