☰ Year plan · Science

Acid rain damage, scrubbers, monitoring and models

Week 14 · 2-4 The Atmosphere and the Role of Science in Its Sustainability (B): effects of acid rain on plants, soil and buildings, scrubbers, monitoring by satellites and weather stations, climate models, forecasting and examples · 3 lessons
1

What acid rain does, and how scrubbers help

Integrated Science Sec 1 Term 1, Unit 2: pp. 103–108
GoalDescribe the damage acid rain does to plants, soil and buildings, and how scrubbers cut the gases that cause it.
New words
leaching · washing useful minerals out of the soillimestone · a rock made mainly of calcium carbonate, CaCO₃scrubber · a unit in a chimney that removes sulphur and nitrogen oxides before the gases leave
Explanation

Acid rain harms plants: the gases SO₂ and NO₂ enter through the stomata and harm the cells of the leaf; chlorophyll breaks down and the stomata are blocked or misshapen, so less CO₂ is absorbed and less glucose is made. Acid rain also washes (leaches) calcium and magnesium out of the soil, which then loses fertility. It attacks limestone (calcium carbonate) in buildings and monuments: H₂SO₄ + CaCO₃ → CaSO₄ + CO₂ + H₂O. Forests, water and wild plants become less productive, biodiversity falls, and air and water quality fall, with costs for health and the economy. Science and technology help. Scrubbers in factory and power-station chimneys remove sulphur and nitrogen oxides before they leave. Scrubbers remove SO₂ and nitrogen oxides, not CO₂. Clean energy (solar, wind, hydropower) makes none of these oxides. Acid rain is not caused by CO₂ alone, since normal rain is already slightly acidic, and it does not burn skin.

H2SO4 + CaCO3→CaSO4 + CO2 + H2O
acid attacks limestone
Worked examples
Balance check for H₂SO₄ + CaCO₃ → CaSO₄ + CO₂ + H₂O. Ca: 1 = 1. S: 1 = 1. C: 1 = 1. H: 2 = 2. O: 4 + 3 = 7 and 4 + 2 + 1 = 7.
Check the masses (Ca = 40, S = 32, C = 12, O = 16, H = 1). CaCO₃ is 100 and H₂SO₄ is 98, so the left side is 198. CaSO₄ is 136, CO₂ is 44 and H₂O is 18, so the right side is 198. Mass is conserved.
A scrubber removes 90% of the sulphur dioxide. Invented numbers: a chimney would send out 200 tonnes a year, so the scrubber takes out 0.9 × 200 = 180 tonnes and 20 tonnes remain. Less SO₂ means less acid rain.
Class activity

Chalk or eggshell in vinegar, with a grown-up who handles the vinegar. Put a piece of chalk or eggshell in a cup of vinegar and another in a cup of water. Watch from a distance for a few minutes. Do not taste or sniff. Describe what changes, and say what this tells you about acid and calcium carbonate. Then draw a paper model of a scrubber: a chimney with a filter box that holds back the oxides. No smoke, gas or water spray.

Practice
1
Why does acid rain reduce photosynthesis?
2
What does acid rain wash out of the soil?
3
Which gases do scrubbers remove, and which do they not remove?
4
A scrubber removes 80% of 50 tonnes of SO₂. How many tonnes remain?