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Heating curves, melting and boiling points

الأسبوع 2 · الدرس الثاني «تغير حالات المادة» (١): منحنى تسخين الماء والطاقة وحركة الجسيمات ودرجتا الانصهار والغليان وأثر الضغط والشوائب · 3 دروس
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What shifts melting and boiling points: pressure and purity

Science Prep 2 Term 1, Unit 1: pp. 10–14
GoalExplain how pressure and impurities change melting and boiling points, and use a table of melting and boiling points to find a state.
New words
atmospheric pressure · the pressure of the air above usimpurity · something extra mixed into a pure substancepure substance · a substance with nothing else mixed into it
Explanation

At a given pressure, every pure substance melts and boils at its own set temperatures, called its melting point and boiling point. Water boils at 100 °C only at sea level. Higher pressure raises the boiling point: in a pressure cooker, steam is trapped, the water boils above 100 °C and food cooks faster (adults only use it). Lower pressure lowers the boiling point: on a mountain, water boils at a lower temperature, about 1 °C lower for every 300 m, so food takes longer to cook. Impurities also change the points: a salty solution boils a little higher and freezes lower than pure water, which is why salt is spread on icy roads. Because pure substances have fixed points, we can check purity by measuring a melting or boiling point and comparing it with the known value. To tell the state from a table: below the melting point a substance is solid, between the two points it is liquid, above the boiling point it is a gas.

Rounded, for illustration
Height above sea levelBoiling point of water (about)
0 m100 °C
900 m97 °C
2400 m92 °C
3000 m90 °C
Worked examples
SubstanceMelting point (°C)Boiling point (°C)
P−780
Q40200
R−110−35
A table lists three substances (melting point / boiling point): P −7 / 80 °C, Q 40 / 200 °C, R −110 / −35 °C. At 25 °C, P is a liquid (between −7 and 80), Q is a solid (below 40) and R is a gas (above −35).
Sample X is said to be pure water. It freezes at −1.5 °C and not at 0 °C. Because a pure substance freezes at a fixed point, X is not pure water: it has something dissolved in it.
Why does a pot of rice take longer to cook on a high mountain? Water boils there below 100 °C, so the cooking water is cooler than at sea level.
Class activity

Boiling-point detective. Draw a graph of the table in this lesson: height (0 to 3000 m) across and boiling point (88 to 100 °C) up the side. Join the points with a line. Use it to estimate the boiling point at 1500 m. Then write two sentences on why a pressure cooker cooks faster and why it is for adults only.

Practice
1
Does higher pressure raise or lower the boiling point of water?
2
Using the table in this lesson, estimate the boiling point of water at 1500 m.
3
A substance melts at 20 °C and boils at 150 °C. What state is it at 100 °C? At 10 °C?
4
Why is salt spread on icy roads?