الأسبوع 4 · الباب الأول (٤): الحديد في الطبيعة وخاماته وتجهيز الخام والتحميص واختزال الخام في الفرن العالي وفرن الغاز وإنتاج الحديد الزهر والصلب وأنواع السبائك الثلاثة (وصف مفاهيمي للعمليات الصناعية) · 3 دروس
GoalDefine an alloy and tell the three types, interstitial, substitutional and intermetallic, apart by atom size and by example.
New words
alloy · a metal mixed with one or more other elements, usually other metals, that still behaves as a metalinterstitial alloy · small atoms such as carbon sit in the gaps of the host metal’s latticesubstitutional alloy · atoms of nearly the same size and chemistry take the places of host atomsintermetallic compound · a true compound of metals with a fixed formula that does not follow the usual valence rules
Explanation
An alloy is a metal mixed with other elements, usually other metals but sometimes a non-metal. Steel is iron with carbon; ferrochrome, ferromanganese, ferrovanadium and ferronickel are iron with another metal. In industry alloys are made by melting the parts together and cooling slowly, or by depositing metals together from a solution. Three types depend on atom size and chemistry. In an interstitial alloy small atoms, such as carbon or nitrogen, sit in the gaps between large metal atoms; the layers of the host can no longer slide so easily and the metal is harder. Steel is the main example. In a substitutional alloy atoms of nearly the same size and chemistry replace one another: chromium (about 128 pm) in iron (about 126 pm) gives stainless steel, and zinc in copper gives brass. An intermetallic compound is a real compound with a fixed ratio that does not follow the usual valence rules, such as Au₂Pb or Fe₃C (iron carbide). Duralumin is an aluminium alloy, used where low mass and strength are both needed.
Type
Atom sizes
How the atoms fit
Example
interstitial
foreign atom much smaller
in the gaps
steel (C in Fe)
substitutional
nearly equal
swap places
stainless steel (Cr in Fe), brass
intermetallic
—
fixed formula, a compound
Fe₃C, Au₂Pb
Worked examples
Classify by atom size (approximate radii: Fe 126 pm, Cr 128 pm, C 77 pm). Carbon is much smaller than iron, so its atoms fit in the gaps: an interstitial alloy, which is steel. Chromium is almost the same size as iron, so its atoms swap places: a substitutional alloy, which is stainless steel.
Why alloys are harder than the pure metal. In a pure metal the layers of identical atoms slide over each other fairly easily. A foreign atom of another size sits in the way and blocks the sliding, so more force is needed to bend the metal.
A compound with a fixed formula. In Fe₃C there are 3 Fe atoms for each C atom (Fe = 56, C = 12): M = 3 × 56 + 12 = 180 g/mol, and carbon is 12 ÷ 180 × 100 = 6.67 % by mass. An interstitial alloy has no such fixed ratio: its carbon content can change smoothly.
Class activity
A model with coins, no heating. Lay a flat layer of identical coins on a table and slide a second layer over it: see how easily it moves. Now scatter a few lentils between the layers, or swap one coin for a bigger one, and slide again. Write what you notice and which type of alloy each change models (lentils: interstitial, different-size coin: a foreign atom). Say honestly where the model is not right.
Practice
1
Nickel (about 124 pm) is alloyed with copper (about 128 pm). Which type of alloy is formed, and why?
Substitutional: the atoms are nearly the same size, so they can replace one another in the lattice.
2
Nitrogen atoms (about 70 pm) dissolve in iron. Which type of alloy is this?
Interstitial: nitrogen is much smaller than iron, so it fits in the gaps.
3
Why is Au₂Pb called an intermetallic compound?
It has a fixed formula, 2 Au to 1 Pb, that does not follow the usual valence rules. It is a real compound of two metals.
4
Find the mass percentage of copper in the intermetallic compound CuZn (Cu = 63.5, Zn = 65).
M = 63.5 + 65 = 128.5 g/mol; % Cu = 63.5 ÷ 128.5 × 100 = 49.4 %.