☰ خطة العام · الكيمياء (بالإنجليزية)

The d block and the first series in use

الأسبوع 1 · الباب الأول «العناصر الانتقالية» (١): المقدمة والأهداف والعناصر الانتقالية الرئيسية والداخلية والسلاسل الانتقالية الأربع والسلسلة الأولى من Sc إلى Zn واستخدامات كل عنصر منها · 3 دروس
3

The first series in use: iron to zinc

Chemistry Sec 3 Term 1, Chapter 1: pp. 1–8
GoalLink iron, cobalt, nickel, copper and zinc to a useful property and a use.
New words
galvanising · coating iron or steel with zinc so that it does not rustmagnetised · made into a magnet; iron, cobalt and nickel can all be magnetisedcatalyst · a substance that speeds up a reaction and is not used up; iron and finely divided nickel are examples
Explanation

Iron is the metal of heavy industry: reinforced concrete, electricity pylons, rails and tools are made of it, and iron is also the catalyst in making ammonia. Cobalt can be magnetised like iron, so it is used in strong magnets and in rechargeable cells; its form cobalt-60 gives gamma rays used to inspect welds, a job for trained people only. Nickel gives hard steels that resist rust, rechargeable cells, a nickel–chromium alloy for heating coils (it resists corrosion when hot), shiny plating and, as a fine powder, a catalyst that hardens oils. Copper was one of the first metals people worked; with tin it makes bronze, and it carries electricity well, so it fills cables and coins. Copper(II) sulphate is used against fungi on crops. Fehling’s solution, a blue copper compound, turns orange-red with some sugars such as glucose: a laboratory test, not for home. Zinc coats iron (galvanising) to protect it, ZnO goes into paints, rubber and cosmetics, and ZnS is used in luminous paints and screens.

ElementProperty that mattersUse
ironstrong, cheap, magneticconcrete reinforcement, pylons, rails, catalyst for ammonia
cobaltcan be magnetisedmagnets, rechargeable cells
nickelresists rust and acidshard steels, heating coils, plating, catalyst for oils
copperconducts electricity wellcables, coins, bronze
zincprotects irongalvanising, ZnO in paints, ZnS in luminous paints
Worked examples
Galvanising. A steel pylon is coated with zinc. The zinc layer is a barrier against air and water, so the iron underneath does not rust. The coating is the use; the property behind it is that zinc itself corrodes only very slowly in air.
AlloyMade fromProperty used
bronzecopper + tinhard, easy to cast
heating coil alloynickel + chromiumresists corrosion when hot
steeliron + carbonstrong and hard
Which metal is the main one in each alloy? Bronze is copper with tin: the main metal is copper. A heating coil is nickel with chromium: the main metal is nickel. Steel is iron with a little carbon: an alloy of a metal with a non-metal.
A property that three metals share. Iron, cobalt and nickel can all be magnetised, so all three appear in magnets. Copper and zinc cannot, so a magnet will not pick up a pure copper wire or a zinc sheet. “Transition element” does not mean “magnetic”.
Class activity

A magnet test, with a grown-up. Hold a fridge magnet near an iron nail, a steel fork, a ball of aluminium foil and a coin, and make a table of object and attracted: yes or no. Iron and steel are clearly attracted. Some coins have a steel core, so if yours is attracted you have learned something about that coin. Then compare a steel nail and a copper-coloured coin by shine, colour and how heavy each feels. Optional extra: put a copper-coloured coin in a cup of cold vinegar with a pinch of salt and see what happens after some minutes. Do not taste anything, wash your hands afterwards and pour the liquid away with water.

Practice
1
Which metal of this lesson is used (a) for cables, (b) for galvanising, (c) as the catalyst in making ammonia?
2
Name the alloy of copper and tin, and the metal alloyed with nickel in heating coils.
3
Why is a galvanised nail less likely to rust than a plain nail?
4
What do iron, cobalt and nickel share that copper and zinc do not, among the uses in this lesson?